It is not secret that I do not like V for Vendetta. I have a problem with the tone of the movie, the script of the movie, and the fact that you are rooting for the villain in the movie.
Well guess what "movie" does what V for Vendetta did, but with a double punch of awesome and awesome-r. Dr. Horrible's Sing-Along Blog.
This short film does a much better job of showing why some evil people are good and some good people are evil, and gets me to actually root for the villain. Other pluses are that it is funny, free, and a click away. Watch it.